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Degree of ionization

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Degree of ionization

A plasma lamp, illustrating a low degree of ionization (i.e. a partially ionized gas)

The degree of ionization (also known as ionization yield in the literature) refers to the proportion of neutral particles, such as those in a gas or aqueous solution, that are ionized to charged particles. A low degree of ionization is sometimes called partially ionized, and a very high degree of ionization as fully ionized.

Ionization refers to the process whereby an atom or molecule loses an electron, resulting in two oppositely charged particles, (1) a negatively charged electron and (2) a positively charged ion.

Contents

  • Chemistry usage 1
  • Physics usage 2
  • History 3
  • See also 4
  • Footnotes 5

Chemistry usage

The degree of dissociation α (sometimes also degree of ionization), is a way of representing the strength of an acid. It is defined as the ratio of the number of ionized molecules and the number of molecules dissolved in water. It can be represented as a decimal number or as a percentage. One can classify strong acids as those having ionization degrees above 30%, weak acids as those with α below 30%, and the rest as moderate acids, at a specified molar concentration.

Physics usage

In gases and plasma, the degree of ionization refers to the proportion of neutral particles that are ionized into charged particles. For example, when electricity passes through a novelty plasma ball, perhaps 1% of the gases are ionized (sometimes referred to as partially ionized). Our Sun and all stars contain largely hydrogen and helium gases, that are fully ionized into electrons, protons (H+) and helium ions (He++).

A gas may begin to behave like plasma when the degree of ionization is as little as 0.01%.[1]

[2]

History

Ionized matter was first identified in a discharge tube (or Crookes tube), and so described by Sir William Crookes in 1879 (he called it "radiant matter").[3] The nature of the Crookes tube "cathode ray" matter was subsequently identified by English physicist Sir J.J. Thomson in 1897,[4] and dubbed "plasma" by Irving Langmuir in 1928,[5] perhaps because it reminded him of a blood plasma.[6]

See also

Footnotes

  1. ^ Brian Chapman, "Glow discharge plasmas." p49
  2. ^ Shibamoto, Takayuki. Introduction to Food Toxicology, 2nd Edition. Academic Press, 2009. p17.
  3. ^ Crookes presented a lecture to the British Association for the Advancement of Science, in Sheffield, on Friday, 22 August 1879 [4] [5]
  4. ^ Announced in his evening lecture to the Royal Institution on Friday, 30 April 1897, and published in Philosophical Magazine, 44, 293 [6]
  5. ^ I. Langmuir, "Oscillations in ionized gases," Proc. Nat. Acad. Sci. U.S., vol. 14, p. 628, 1928
  6. ^ G. L. Rogoff, Ed., IEEE Transactions on Plasma Science, vol. 19, p. 989, Dec. 1991. See extract at http://www.plasmacoalition.org/what.htm
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