World Library  
Flag as Inappropriate
Email this Article

Realgar

Article Id: WHEBN0000875336
Reproduction Date:

Title: Realgar  
Author: World Heritage Encyclopedia
Language: English
Subject: Arsenic, Uranium disulfide, Mineralogy, Hauerite, History of poison
Collection:
Publisher: World Heritage Encyclopedia
Publication
Date:
 

Realgar

Realgar
Realgar crystals, Royal Reward Mine, King County, Washington, USA
General
Category Sulfide mineral
Formula
(repeating unit)
As4S4 or AsS
Strunz classification 02.FA.15a
Crystal symmetry Monoclinic 2/m
Unit cell a = 9.325(3) Å,
b = 13.571(5) Å,
c = 6.587(3) Å,
β = 106.43°; Z=16
Identification
Color Red to yellow-orange; in polished section, pale gray, with abundant yellow to red internal reflections
Crystal habit Prismatic striated crystals; more commonly massive, coarse to fine granular, or as incrustations
Crystal system Monoclinic prismatic
Twinning Contact twins on {100}
Cleavage Good on {010}; less so on {101}, {100}, {120}, and {110}
Tenacity Sectile, slightly brittle
Mohs scale hardness 1.5–2
Luster Resinous to greasy
Streak Red-orange to red
Diaphaneity Transparent
Specific gravity 3.56
Optical properties Biaxial (-)
Refractive index nα = 2.538
nβ = 2.684
nγ = 2.704
Birefringence δ = 0.166
Pleochroism Nearly colorless to pale golden yellow
2V angle 40°
Dispersion r > v, very strong
Other characteristics

Toxic and carcinogenic.

Disintegrates on long exposure to light to a powder composed of pararealgar or arsenolite and orpiment.
References [1][2][3][4]

Realgar, α-As4S4, is an arsenic sulfide mineral, also known as "ruby sulphur" or "ruby of arsenic". It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related mineral, orpiment (As2S3). It is orange-red in colour, melts at 320 °C, and burns with a bluish flame releasing fumes of arsenic and sulfur. Realgar is soft with a Mohs hardness of 1.5 to 2 and has a specific gravity of 3.5. Its streak is orange colored. It is trimorphous with alacranite and pararealgar.[1] Its name comes from the Arabic rahj al-ġār (رهج الغار, "powder of the mine"), via Catalan and Medieval Latin, and its earliest record in English is in the 1390s.[5]

Occurrence

Realgar most commonly occurs as a low-temperature hydrothermal vein mineral associated with other arsenic and antimony minerals. It also occurs as volcanic sublimations and in hot spring deposits. It occurs in association with orpiment, arsenolite, calcite and barite.[1]

It is found with lead, silver and gold ores in Hungary, Bohemia and Saxony. In the US it occurs notably in Mercur, Utah; Manhattan, Nevada and in the geyser deposits of Yellowstone National Park.[4]

It is commonly held that after a long period of exposure to light realgar changes form to a yellow powder known as pararealgar (β-As4S4). It was once thought that this powder was the yellow sulfide orpiment, but has been recently shown to be a distinct chemical compound.

Uses

Realgar, orpiment, and arsenopyrite provide nearly all the world's supply of arsenic as a byproduct of smelting concentrates derived from these ores.

Realgar was used by firework manufacturers to create the color white in fireworks prior to the availability of powdered metals such as aluminium, magnesium and titanium. It is still used in combination with potassium chlorate to make a contact explosive known as "red explosive" for some types of torpedoes and other novelty exploding fireworks branded as 'cracker balls', as well in the cores of some types of crackling stars.

Realgar is toxic. The ancient Greeks, who called it "sandaracha", understood it is poisonous. It was used to poison rats in medieval Spain and in 16th century England.[6] It is still sometimes used to kill weeds, insects, and rodents,[7] even though more effective arsenic-based agents are available.

The Chinese name for realgar is xionghuang 雄黃, literally 'masculine yellow', as opposed to orpiment which was 'feminine yellow'. Its toxicity was also well known to them, and it was frequently sprinkled around houses to repel snakes and insects, as well as being used in Chinese medicine.[8] Realgar is mixed with rice liquor to make realgar wine, which is consumed during the Dragon Boat Festival in order to ward off evil, alluding to its repellent properties. (This practice has become rarer in modern times, with the awareness that realgar is a toxic arsenic compound.)

Realgar was commonly applied in leather manufacturing to remove the hair from animal pelts. Because realgar is a known carcinogen, and an arsenic poison, and because competitive substitutes are available, it is rarely used today for this purpose.

Realgar was, along with orpiment, a significant item of trade in the ancient Roman Empire and was used as a red paint pigment. Early occurrences of realgar as a red painting pigment are known for works of art from China, India, Central Asia, and Egypt. It was used in European fine-art painting during the Renaissance era, a use which died out by the 18th century.[9] It was also used as medicine.

Other traditional uses include manufacturing lead shot, printing and dyeing calico cloth.

Realgar gallery

See also

References

  1. ^ a b c Handbook of Mineralogy
  2. ^ Realgar at Mindat.org
  3. ^ Realgar at Webmineral
  4. ^ a b Klein, Cornelis and Cornelius S. Hurlbut, Manual of Mineralogy, Wiley, 1985, 20th ed., p. 282 ISBN 0-471-80580-7
  5. ^ Philip Babcock Grove, ed. (1993). Webster's Third New International Dictionary. Merriam-Webster, inc.  
  6. ^ ref, ref (in French).
  7. ^ See e.g. Hazardous Substance Factsheet for Realgar published by New Jersey Department of Environmental Protection (dated April 2008).
  8. ^ On the toxicity of these medications
  9. ^ , BostonMuseum of Fine Arts

Further reading

  • The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals. 11th Edition. Ed. Susan Budavari. Merck & Co., Inc., N.J., U.S.A. 1989.
  • William Mesny. Mesny’s Chinese Miscellany. A Text Book of Notes on China and the Chinese. Shanghai. Vol. III, (1899), p. 251; Vol. IV, (1905), pp. 425–426.
  • American Mineralogist Vol 80, pp 400–403, 1995 [1]
  • American Mineralogist Vol 20, pp 1266–1274, 1992 [2]

External links

  • Mindat.org: Pararealgar
This article was sourced from Creative Commons Attribution-ShareAlike License; additional terms may apply. World Heritage Encyclopedia content is assembled from numerous content providers, Open Access Publishing, and in compliance with The Fair Access to Science and Technology Research Act (FASTR), Wikimedia Foundation, Inc., Public Library of Science, The Encyclopedia of Life, Open Book Publishers (OBP), PubMed, U.S. National Library of Medicine, National Center for Biotechnology Information, U.S. National Library of Medicine, National Institutes of Health (NIH), U.S. Department of Health & Human Services, and USA.gov, which sources content from all federal, state, local, tribal, and territorial government publication portals (.gov, .mil, .edu). Funding for USA.gov and content contributors is made possible from the U.S. Congress, E-Government Act of 2002.
 
Crowd sourced content that is contributed to World Heritage Encyclopedia is peer reviewed and edited by our editorial staff to ensure quality scholarly research articles.
 
By using this site, you agree to the Terms of Use and Privacy Policy. World Heritage Encyclopedia™ is a registered trademark of the World Public Library Association, a non-profit organization.
 



Copyright © World Library Foundation. All rights reserved. eBooks from World eBook Library are sponsored by the World Library Foundation,
a 501c(4) Member's Support Non-Profit Organization, and is NOT affiliated with any governmental agency or department.